Not only did she recently announce her pregnancy and engagement between promoting new film No Strings Attached, she is now the face of Christian Dior.
A stunning Miss Portman is pictured advertising perfume Miss Dior Cherie wearing nothing but a black headband - but still remains the picture of innocence.
The French fashion house snapped her up earlier this year and the secret was out when she was photographed on set filming the ads in July.
The actress, expecting her first child with choreographer Benjamin Millepied, shot the campaign, due to appear in March, with photographer Tim Walker and also stars in commercials directed by Sophia Coppola.
And the 29-year-old philanthropist has even gotten the iconic label to support some of her charitable causes.
She said: 'I had an aversion to selling things.
'And then I realised both that there could be a company that I would be proud to represent, and also that they would really support the things I believe in.
'It’s really wonderful to have this established, elegant brand willing to do great non-profit work.'
Miss Portman was pictured looking radiant at the premiere of No Strings attached last night, also starring Ashton Kutcher.
They play a couple attempting to keep their relationship purely physical, but begin to develop feelings for each other.
Portman, who lost 20lbs for her role in Black Swan, told Extra at the Palm Springs International Film Festival Saturday: 'I told director Darren Aronofsky, I was like, "First you got me skinny, and now you're getting my fat," because he introduced me to my fiance.
She's very pretty and youthful, but I feel like she's a little too old for Chérie at 30.
She's 29.
I do agree, she's too old. Maryna Linchuk and Riley Keough (Elvis' Granddaughter) were the previous faces of the fragrance. Riley was only 16 or 17 at the time.
I do agree, she's too old. Maryna Linchuk and Riley Keough (Elvis' Granddaughter) were the previous faces of the fragrance. Riley was only 16 or 17 at the time.
I hate when women over 25 act all cutesy and girly
I hate when women over 25 act all cutesy and girly
I don't like it either, it seems kind of desperate. I think she pulls it off in this instance though. She does not look her age, it must be the vegetarian diet.