My favorite is either Thinking Of You or Teenage Dream. And the song I like the least is probably Last Friday Night. Or Milk Milk Lemonade if that one counts.
Most favorite: I don't enjoy it anymore, but probably it's Roar. I haven't listened to a song by hers as much as I have listened to Roar
Least favorite: Every song on second half of Prism sans Choose Your Battles.